@prefix biopax:  <http://www.biopax.org/release/biopax-level3.owl#> .
@prefix cito:    <http://purl.org/spar/cito/> .
@prefix dc:      <http://purl.org/dc/elements/1.1/> .
@prefix dcterms: <http://purl.org/dc/terms/> .
@prefix foaf:    <http://xmlns.com/foaf/0.1/> .
@prefix freq:    <http://purl.org/cld/freq/> .
@prefix gpml:    <http://vocabularies.wikipathways.org/gpml#> .
@prefix obo:     <http://purl.obolibrary.org/obo/> .
@prefix owl:     <http://www.w3.org/2002/07/owl#> .
@prefix pav:     <http://purl.org/pav/> .
@prefix prov:    <http://www.w3.org/ns/prov#> .
@prefix rdf:     <http://www.w3.org/1999/02/22-rdf-syntax-ns#> .
@prefix rdfs:    <http://www.w3.org/2000/01/rdf-schema#> .
@prefix skos:    <http://www.w3.org/2004/02/skos/core#> .
@prefix void:    <http://rdfs.org/ns/void#> .
@prefix wp:      <http://vocabularies.wikipathways.org/wp#> .
@prefix wprdf:   <http://rdf.wikipathways.org/> .
@prefix xsd:     <http://www.w3.org/2001/XMLSchema#> .

<https://identifiers.org/chebi/CHEBI:57945>
        rdf:type            wp:Metabolite , wp:DataNode ;
        rdfs:label          "NADH" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/BOPGDPNILDQYTO-NNYOXOHSSA-N> ;
        dc:identifier       <https://identifiers.org/chebi/CHEBI:57945> ;
        dc:source           "ChEBI" ;
        dcterms:identifier  "57945" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:57945> ;
        wp:bdbChemspider    <https://identifiers.org/chemspider/10239197> ;
        wp:bdbInChIKey      <https://identifiers.org/inchikey/BOPGDPNILDQYTO-NNYOXOHSSA-L> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID21604869> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q27125072> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/ddd30> ;
        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=57945> .

<https://identifiers.org/sgd/S000000349>
        rdf:type            wp:GeneProduct , wp:DataNode ;
        rdfs:label          "ADH5" ;
        dc:identifier       <https://identifiers.org/sgd/S000000349> ;
        dc:source           "SGD" ;
        dcterms:identifier  "S000000349" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbEnsembl       <https://identifiers.org/ensembl/YBR145W> ;
        wp:bdbEntrezGene    <https://identifiers.org/ncbigene/852442> ;
        wp:bdbUniprot       <https://identifiers.org/uniprot/P38113> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/ebf11> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/P38113> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000000349> .

<https://identifiers.org/chebi/CHEBI:16810>
        rdf:type            wp:DataNode , wp:Metabolite ;
        rdfs:label          "2-oxoglutarate" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/KPGXRSRHYNQIFN-UHFFFAOYSA-N> ;
        dc:identifier       <https://identifiers.org/chebi/CHEBI:16810> ;
        dc:source           "ChEBI" ;
        dcterms:identifier  "16810" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:16810> ;
        wp:bdbChemspider    <https://identifiers.org/chemspider/144236> ;
        wp:bdbInChIKey      <https://identifiers.org/inchikey/KPGXRSRHYNQIFN-UHFFFAOYSA-L> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID164533> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q27102088> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/add87> ;
        owl:sameAs          <https://swisslipids.org/rdf/SLM_000389931> ;
        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=16810> .

<https://identifiers.org/sgd/S000001251>
        rdf:type            wp:GeneProduct , wp:DataNode ;
        rdfs:label          "BAT1" ;
        dc:identifier       <https://identifiers.org/sgd/S000001251> ;
        dc:source           "SGD" ;
        dcterms:identifier  "S000001251" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbEnsembl       <https://identifiers.org/ensembl/YHR208W> ;
        wp:bdbEntrezGene    <https://identifiers.org/ncbigene/856615> ;
        wp:bdbUniprot       <https://identifiers.org/uniprot/P38891> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/ebb> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/P38891> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000001251> .

<https://identifiers.org/pubmed/15933030>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
        dcterms:identifier  "15933030" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/15933030> .

<https://identifiers.org/sgd/S000003225>
        rdf:type            wp:DataNode , wp:GeneProduct ;
        rdfs:label          "ADH4" ;
        dc:identifier       <https://identifiers.org/sgd/S000003225> ;
        dc:source           "SGD" ;
        dcterms:identifier  "S000003225" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbEnsembl       <https://identifiers.org/ensembl/YGL256W> ;
        wp:bdbEntrezGene    <https://identifiers.org/ncbigene/852636> ;
        wp:bdbUniprot       <https://identifiers.org/uniprot/P10127> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/fa452> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/P10127> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000003225> .

<https://identifiers.org/pubmed/9546164>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
        dcterms:identifier  "9546164" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/9546164> .

<https://identifiers.org/cas/61-90-5>
        rdf:type            wp:DataNode , wp:Metabolite ;
        rdfs:label          "L-leucine" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/ROHFNLRQFUQHCH-YFKPBYRVSA-N> ;
        dc:identifier       <https://identifiers.org/cas/61-90-5> ;
        dc:source           "CAS" ;
        dcterms:identifier  "61-90-5" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:15603> , <https://identifiers.org/chebi/CHEBI:57427> ;
        wp:bdbChemspider    <https://identifiers.org/chemspider/5880> ;
        wp:bdbHmdb          <https://identifiers.org/hmdb/HMDB0000687> ;
        wp:bdbInChIKey      <https://identifiers.org/inchikey/ROHFNLRQFUQHCH-YFKPBYRVSA-N> ;
        wp:bdbKeggCompound  <https://identifiers.org/kegg.compound/C00123> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID7045798> , <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID6106> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q106345666> , <http://www.wikidata.org/entity/Q483745> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/f61> ;
        foaf:page           <https://commonchemistry.cas.org/detail?cas_rn=61-90-5> .

obo:NCBITaxon_4932  obo:NCIT_C179773  "4932" .

<https://identifiers.org/pubmed/8798704>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
        dcterms:identifier  "8798704" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/8798704> .

<https://identifiers.org/wikipathways/WP354_r140497>
        rdf:type               wp:Pathway , skos:Collection ;
        dc:identifier          <https://identifiers.org/wikipathways/WP354> ;
        dc:source              "WikiPathways" ;
        dc:title               "Leucine degradation"@en ;
        dcterms:description    "While Saccharomyces cerevisiae can use most amino acids as their sole nitrogen source, they can only use a few amino acids as a carbon source to support growth (CITS:[Large86][Cooper82]).  This is in contrast to most eukaryotes and some fungi, which can metabolize amino acids completely, utilizing them as sole sources of carbon and nitrogen (CITS:[Stryer88][Large 86]). S. cerevisiae degrade the branched-chain amino acids (leucine, iso-leucine, and valine) and the aromatic amino acids (tryptophan, phenylalanine, and tyrosine) via the Ehrlich pathway (CITS:[Sentheshanmuganathan60][10989420]).  This pathway is comprised of the following steps:  1) deamination of the amino acid to the corresponding alpha-keto acid; 2) decarboxylation of the resulting alpha-keto acid to the respective aldehyde; and, 3) reduction of the aldehyde to form the corresponding long chain or complex alcohol, known as a fusel alcohol or fusel oil (CITS:[10989420][Large 86]).  Fusel alcohols are important flavor and aroma compounds in yeast-fermented food products and beverages (as reported in (CITS:[9546164]).  Each of the three steps in branched-chain amino acid degradation can be catalyzed by more than one isozyme; which enzyme is used appears to depend on the amino acid, the carbon source and the stage of growth of the culture (CITS:[12499363]). In leucine degradation, Thi3p is believed to be the major decarboxylase (CITS: [12499363]). \nSOURCE: [SGD pathways](http://pathway.yeastgenome.org/server.html)" ;
        dcterms:identifier     "WP354" ;
        dcterms:references     <https://identifiers.org/pubmed/10989420> , <https://identifiers.org/pubmed/12499363> , <https://identifiers.org/pubmed/10989445> , <https://identifiers.org/pubmed/15933030> , <https://identifiers.org/pubmed/8798704> , <https://identifiers.org/pubmed/9748245> , <https://identifiers.org/pubmed/8702755> , <https://identifiers.org/pubmed/9546164> , <https://identifiers.org/pubmed/9341119> ;
        cito:cites             <https://identifiers.org/pubmed/12499363> , <https://identifiers.org/pubmed/10989445> , <https://identifiers.org/pubmed/9748245> , <https://identifiers.org/pubmed/9341119> , <https://identifiers.org/pubmed/15933030> , <https://identifiers.org/pubmed/9546164> , <https://identifiers.org/pubmed/10989420> , <https://identifiers.org/pubmed/8798704> , <https://identifiers.org/pubmed/8702755> ;
        wp:isAbout             <http://rdf.wikipathways.org/Pathway/WP354_r140497> ;
        wp:ontologyTag         obo:PW_0000002 , wp:Curation:AnalysisCollection , obo:PW_0001271 ;
        wp:organism            obo:NCBITaxon_4932 ;
        wp:organismName        "Saccharomyces cerevisiae" ;
        wp:pathwayOntologyTag  obo:PW_0001271 , obo:PW_0000002 ;
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        foaf:page              <http://www.wikipathways.org/instance/WP354_r140497> .

<https://identifiers.org/chebi/CHEBI:16526>
        rdf:type            wp:DataNode , wp:Metabolite ;
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        dc:source           "ChEBI" ;
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        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID280> ;
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        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=16526> .

<https://identifiers.org/chebi/CHEBI:57540>
        rdf:type            wp:DataNode , wp:Metabolite ;
        rdfs:label          "NAD+" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/BAWFJGJZGIEFAR-NNYOXOHSSA-N> ;
        dc:identifier       <https://identifiers.org/chebi/CHEBI:57540> ;
        dc:source           "ChEBI" ;
        dcterms:identifier  "57540" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:57540> ;
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        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID15938971> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q28529711> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/f4bd8> ;
        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=57540> .

<https://identifiers.org/chebi/CHEBI:17865>
        rdf:type            wp:Metabolite , wp:DataNode ;
        rdfs:label          "4-methyl-2-oxopentanoate" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/BKAJNAXTPSGJCU-UHFFFAOYSA-N> ;
        dc:identifier       <https://identifiers.org/chebi/CHEBI:17865> ;
        dc:source           "ChEBI" ;
        dcterms:identifier  "17865" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:17865> ;
        wp:bdbChemspider    <https://identifiers.org/chemspider/2766269> ;
        wp:bdbInChIKey      <https://identifiers.org/inchikey/BKAJNAXTPSGJCU-UHFFFAOYSA-M> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID3527278> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q27102672> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/ad615> ;
        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=17865> .

<https://identifiers.org/cas/56-86-0>
        rdf:type            wp:Metabolite , wp:DataNode ;
        rdfs:label          "L-glutamate" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/WHUUTDBJXJRKMK-VKHMYHEASA-N> ;
        dc:identifier       <https://identifiers.org/cas/56-86-0> ;
        dc:source           "CAS" ;
        dcterms:identifier  "56-86-0" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:16015> ;
        wp:bdbChemspider    <https://identifiers.org/chemspider/30572> ;
        wp:bdbHmdb          <https://identifiers.org/hmdb/HMDB0000148> ;
        wp:bdbInChIKey      <https://identifiers.org/inchikey/WHUUTDBJXJRKMK-VKHMYHEASA-N> ;
        wp:bdbKeggCompound  <https://identifiers.org/kegg.compound/C00025> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID33032> , <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID88747398> , <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID44272391> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q26995161> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/c1c> ;
        foaf:page           <https://commonchemistry.cas.org/detail?cas_rn=56-86-0> .

<https://www.wikipathways.org//wpi/wpi.php?action=downloadFile&type=png&pwTitle=Pathway:WP354&oldid=140497>
        rdf:type        foaf:Image ;
        dcterms:format  "image/png" .

<https://identifiers.org/sgd/S000002788>
        rdf:type            wp:DataNode , wp:GeneProduct ;
        rdfs:label          "ARO10" ;
        dc:identifier       <https://identifiers.org/sgd/S000002788> ;
        dc:source           "SGD" ;
        dcterms:identifier  "S000002788" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbEnsembl       <https://identifiers.org/ensembl/YDR380W> ;
        wp:bdbEntrezGene    <https://identifiers.org/ncbigene/851987> ;
        wp:bdbUniprot       <https://identifiers.org/uniprot/Q06408> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/a915d> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/Q06408> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000002788> .

<https://identifiers.org/pubmed/12499363>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
        dcterms:identifier  "12499363" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/12499363> .

<https://identifiers.org/sgd/S000003909>
        rdf:type            wp:GeneProduct , wp:DataNode ;
        rdfs:label          "BAT2" ;
        dc:identifier       <https://identifiers.org/sgd/S000003909> ;
        dc:source           "SGD" ;
        dcterms:identifier  "S000003909" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbEnsembl       <https://identifiers.org/ensembl/YJR148W> ;
        wp:bdbEntrezGene    <https://identifiers.org/ncbigene/853613> ;
        wp:bdbUniprot       <https://identifiers.org/uniprot/P47176> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/a16> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/P47176> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000003909> .

<https://identifiers.org/wikipathways/WP354>
        pav:hasVersion  <https://identifiers.org/wikipathways/WP354_r140497> .

<https://identifiers.org/chebi/CHEBI:16638>
        rdf:type            wp:Metabolite , wp:DataNode ;
        rdfs:label          "3-methylbutanal" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/YGHRJJRRZDOVPD-UHFFFAOYSA-N> ;
        dc:identifier       <https://identifiers.org/chebi/CHEBI:16638> ;
        dc:source           "ChEBI" ;
        dcterms:identifier  "16638" ;
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        wp:bdbKeggCompound  <https://identifiers.org/kegg.compound/C07329> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID11552> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q409554> ;
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        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=16638> .

<https://identifiers.org/sgd/S000002238>
        rdf:type            wp:DataNode , wp:GeneProduct ;
        rdfs:label          "THI3" ;
        dc:identifier       <https://identifiers.org/sgd/S000002238> ;
        dc:source           "SGD" ;
        dcterms:identifier  "S000002238" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbEnsembl       <https://identifiers.org/ensembl/YDL080C> ;
        wp:bdbEntrezGene    <https://identifiers.org/ncbigene/851479> ;
        wp:bdbUniprot       <https://identifiers.org/uniprot/Q07471> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/cafa2> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/Q07471> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000002238> .

<https://identifiers.org/pubmed/10989445>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
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        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/10989445> .

<https://identifiers.org/pubmed/10989420>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
        dcterms:identifier  "10989420" ;
        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/10989420> .

<https://identifiers.org/pubmed/9341119>
        rdf:type            wp:PublicationReference ;
        dc:source           "PubMed" ;
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        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        foaf:page           <http://www.ncbi.nlm.nih.gov/pubmed/9341119> .

<https://identifiers.org/pubmed/8702755>
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        wp:bdbUniprot       <https://identifiers.org/uniprot/P32771> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/db5> ;
        owl:sameAs          <http://purl.uniprot.org/uniprot/P32771> ;
        foaf:page           <http://www.yeastgenome.org/locus/S000002327> .

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        dc:source           "PubMed" ;
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        rdf:type        foaf:Image ;
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        rdfs:label          "3-methylbutanol" ;
        rdfs:seeAlso        <https://identifiers.org/inchikey/PHTQWCKDNZKARW-UHFFFAOYSA-N> ;
        dc:identifier       <https://identifiers.org/chebi/CHEBI:15837> ;
        dc:source           "ChEBI" ;
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        dcterms:isPartOf    <https://identifiers.org/wikipathways/WP354_r140497> ;
        wp:bdbChEBI         <https://identifiers.org/chebi/CHEBI:15837> ;
        wp:bdbChemspider    <https://identifiers.org/chemspider/29000> ;
        wp:bdbHmdb          <https://identifiers.org/hmdb/HMDB0006007> ;
        wp:bdbInChIKey      <https://identifiers.org/inchikey/PHTQWCKDNZKARW-UHFFFAOYSA-N> ;
        wp:bdbKeggCompound  <https://identifiers.org/kegg.compound/C07328> ;
        wp:bdbLipidMaps     <https://identifiers.org/lipidmaps/LMFA05000108> ;
        wp:bdbPubChem       <http://rdf.ncbi.nlm.nih.gov/pubchem/compound/CID31260> ;
        wp:bdbWikidata      <http://www.wikidata.org/entity/Q223101> ;
        wp:isAbout          <http://rdf.wikipathways.org/Pathway/WP354_r140497/DataNode/c1ce1> ;
        owl:sameAs          <https://www.lipidmaps.org/rdf/LMFA05000108> ;
        foaf:page           <https://www.ebi.ac.uk/chebi/searchId.do?chebiId=15837> .
